Moseley et al. (1984) proposed X-ray microcalorimeters as a
means of simultaneously attaining high spectral resolution and throughput.
In contrast to a bolometer which measures an integrated radiant flux, a
calorimeter measures the energy of individual X-ray photons by the
temperature rise they cause when absorbed in a small sensing element.
The concept of a calorimeter is similar to that of a bolometer. However
it is subject to more stringent design constraints due to
the necessity of thermalizing individual photons rapidly.
Figure 3 is a schematic of an
X-ray microcalorimeter. An X-ray photon hits an absorber
which converts its energy into heat. In its simplest form (
T
T)
the resulting temperature rise is
T =
where E is the energy of the photon and C is
the heat capacity of the calorimeter. This is sensed by a thermometer, typically
consisting of a doped semiconductor. A thermal link to a heat bath conducts heat away from
the calorimeter so that the temperature decays exponentially to the
baseline value with a thermal time constant
=
where G is the
thermal conductance of the link.
For this device to be useful several conditions must be met. The heat
capacity C must be small enough to produce a significant temperature rise.
Because the heat capacities of most of the materials used to construct
calorimeters vary as T3 as T
0 this may be achieved by operating the
device at low temperatures, typically below
100 mK.
For applications over the 1-10 keV band, the absorber is a significant contributor to the total heat capacity.
The main contributor to the
heat capacity of the calorimeter is the absorber. Normal metals such as gold
and silver are excellent absorbers and thermalizers of X-ray photons but their
large electron heat capacities render them unsuitable for practical
devices. Alternative choices for absorbers are semimetals such as HgTe or
superconductors such as tin (e.g. Moseley et al. (1992)).
The absorber must have a high X-ray opacity and a low heat capacity, and
must convert the photon's
energy into phonons in a time much less than
. Superconductors have
lower heat capacities than normal metals. However, in a superconductor
much of the energy of a deposited X-ray goes towards breaking Cooper pairs
into quasiparticles. When these recombine into Cooper pairs this energy is
converted into phonons. One problem is that the quasiparticles can take a
long time to recombine which degrades the resolution. Raising the normal
electron concentration can reduce
this effect. Thus heat capacity and recombination time must be traded off
to obtain optimum performance (Stahle et al. (1993)).